WebJul 22, 2024 · ABSTRACT. We investigate the role of excitonic coupling between retinal chromophores of Krokinobacter eikastus rhodopsin 2 (KR2) in the circular dichroism … WebJun 14, 2012 · The visible CD spectrum of bacteriorhodpsin (bR) in purple membrane has a negative CD band at ~600 nm and a positive band at ~530 nm and has been variously interpreted as resulting from exciton coupling within the bR trimer, heterogeneity in protein conformation, or the presence of two distinct low-energy electronic transitions in bR.
The Exciton Model and the Circular Dichroism of Polypeptides
WebSpin-valley excitons can be optically excited by circularly polarized light at K or K′ valleys, acquiring a valley degree of freedom ( 6 – 8 ). They play a vital role in the optically driven valleytronic devices based on TMDs. Fig. 1 Schematic showing spin-valley dynamics in TMD systems. ( A) The band structure at the band edges near K and K′. WebFeb 2, 2012 · Excitons Abstract The interaction of two IR chromophores yields a strong vibrational circular dichroism couplet whose sign reflects the absolute configuration of the molecule. We present a method to determine absolute configuration of a chiral molecule based on this couplet without need of theoretical calculation. healthy cereal with protein
THE EXCITON MODEL IN MOLECULAR SPECTROSCOPY
WebWe have applied exciton theory to estimate the circular dichroism (CD) contribution of the Trp B transition to the far-UV circular dichroism of globular proteins. Strong exciton … WebExcitons refer to electronic excited states that are not localized to a particular molecule. But beyond that there are many flavors. We will concentrate on Frenkel excitons, which refer to excited states in which the excited electron and the corresponding hole (or electron vacancy) reside on the same molecule. WebThe exciton calculations were supplemented by calculations of the coupling of the retinal transition with aromatic and peptide group transitions. For the dimer, all three methods and three models give a long-wavelength C 2 -axis-polarized band, negative in CD, and a short-wavelength band polarized perpendicular to the C 2 axis with positive CD ... motors30